Holy shitballs I love this picture! This shows The Round Corner House in Charlestown. The street on the right is "Thompson Street" before it was turned into a private driveway. In the distance to the left you can see Thompson Square Station. The view now is so different. Also, I never knew the Round Corner House had two stories torn down. Make sense though because today it has 20' tall chimney (which you can see in that streetview link).
EDIT: Fuck me I'm totally wrong. Here's the picture zoomed out. Still doesn't explain why the Round Corner House has 20' chimneys.